NickelMaghrebV1, France, Analysis, bibRecord, 000126

Crystal structure and magnetic properties of Na2NiII(HPO3)2

Identifieur interne : 000126 ( France/Analysis ); précédent : 000125; suivant : 000127

Crystal structure and magnetic properties of Na2NiII(HPO3)2

Auteurs : Wassim Maalej [France, Tunisie] ; Serge Vilminot [France] ; Zakaria Elaoud [Tunisie] ; Tahar Mhiri [Tunisie] ; Mohamedally Kurmoo [France]

Source :

Journal of solid state chemistry : (Print) [ 0022-4596 ] ; 2010.

RBID : Pascal:11-0019953

Descripteurs français

Pascal (Inist)
- Structure cristalline, Structure magnétique, Propriété magnétique, Lumière verte, Synthèse hydrothermale, Réseau orthorhombique, Groupe espace, Paramètre cristallin, Effet tunnel, Ion sodium, Spectre IR, Susceptibilité magnétique, Antiferromagnétisme, Aimantation, Nickel, Matériau paramagnétique, Matériau antiferromagnétique, Antiferromagnétique, 6166, 7550E.
Wicri :
- topic : Nickel.

English descriptors

KwdEn :
- Antiferromagnetic materials, Antiferromagnetism, Crystal structure, Green light, Hydrothermal synthesis, Infrared spectra, Lattice parameters, Magnetic properties, Magnetic structure, Magnetic susceptibility, Magnetization, Nickel, Orthorhombic lattices, Paramagnetic materials, Sodium ions, Space groups, Tunnel effect.

Abstract

Na₂Ni(HPO₃)₂, obtained as light yellow-green crystals under mild hydrothermal conditions, crystallizes in the orthorhombic Pnma space-group with lattice parameters: a = 11.9886(3), b = 5.3671(2), c=9.0764(3) Å. V₌584.01 Å³, Z₌4. The structure consists of zig-zag chains of Ni0₆ octahedra bridged by two HPO^2-₃ and the chains are further connected through HPO^2-₃ to four nearest chains to form a three dimensional framework, delimiting intersecting tunnels in which the sodium ions are located. The Na cations reside in the irregular Na(1)O₅, Na-O of 2.276-2.745 Å, and Na(2)O₉, Na-O of 2.342-2.376 Å, environments. The presence of the phosphite monoanion has been further confirmed by IR spectroscopy. Due to the 3D framework of Ni connected by O-P-O bridges, the magnetic susceptibility behaves as a paramagnet above 100 K (C = 1.49(2) emu K mol^-1, μ_eff= 3.45 μ_B, Θ= -39(2) K) and below 6 K, it orders antiferromagnetically as confirmed the sharp drop and the non-Brillouin behavior of the isothermal magnetization at 2 K.

Affiliations:

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Pascal:11-0019953

Le document en format XML

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(HPO<sub>3</sub>
)<sub>2</sub>
</title>
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<author><name sortKey="Kurmoo, Mohamedally" sort="Kurmoo, Mohamedally" uniqKey="Kurmoo M" first="Mohamedally" last="Kurmoo">Mohamedally Kurmoo</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Crystal structure and magnetic properties of Na<sub>2</sub>
Ni<sup>II</sup>
(HPO<sub>3</sub>
)<sub>2</sub>
</title>
<author><name sortKey="Maalej, Wassim" sort="Maalej, Wassim" uniqKey="Maalej W" first="Wassim" last="Maalej">Wassim Maalej</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Departement de Chimie des Matériaux Inorganiques, IPCMS, UMR CNRS-UdS 7504, 23 rue du Loess, BP 43</s1>
<s2>67034 Strasbourg</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Alsace (région administrative)</region>
<settlement type="city">Strasbourg</settlement>
</placeName>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de l'Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, BP 802, Route de Soukra</s1>
<s2>3018 Sfax</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>3018 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Vilminot, Serge" sort="Vilminot, Serge" uniqKey="Vilminot S" first="Serge" last="Vilminot">Serge Vilminot</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Departement de Chimie des Matériaux Inorganiques, IPCMS, UMR CNRS-UdS 7504, 23 rue du Loess, BP 43</s1>
<s2>67034 Strasbourg</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Alsace (région administrative)</region>
<settlement type="city">Strasbourg</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Elaoud, Zakaria" sort="Elaoud, Zakaria" uniqKey="Elaoud Z" first="Zakaria" last="Elaoud">Zakaria Elaoud</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de l'Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, BP 802, Route de Soukra</s1>
<s2>3018 Sfax</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>3018 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de l'Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, BP 802, Route de Soukra</s1>
<s2>3018 Sfax</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>3018 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Kurmoo, Mohamedally" sort="Kurmoo, Mohamedally" uniqKey="Kurmoo M" first="Mohamedally" last="Kurmoo">Mohamedally Kurmoo</name>
<affiliation wicri:level="4"><inist:fA14 i1="03"><s1>Laboratoire DECOMET, CNRS-UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal</s1>
<s2>67000 Strasbourg</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Alsace (région administrative)</region>
<settlement type="city">Strasbourg</settlement>
</placeName>
<orgName type="university">Université de Strasbourg</orgName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal of solid state chemistry : (Print)</title>
<title level="j" type="abbreviated">J. solid state chem. : (Print)</title>
<idno type="ISSN">0022-4596</idno>
<imprint><date when="2010">2010</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Journal of solid state chemistry : (Print)</title>
<title level="j" type="abbreviated">J. solid state chem. : (Print)</title>
<idno type="ISSN">0022-4596</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetic materials</term>
<term>Antiferromagnetism</term>
<term>Crystal structure</term>
<term>Green light</term>
<term>Hydrothermal synthesis</term>
<term>Infrared spectra</term>
<term>Lattice parameters</term>
<term>Magnetic properties</term>
<term>Magnetic structure</term>
<term>Magnetic susceptibility</term>
<term>Magnetization</term>
<term>Nickel</term>
<term>Orthorhombic lattices</term>
<term>Paramagnetic materials</term>
<term>Sodium ions</term>
<term>Space groups</term>
<term>Tunnel effect</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Structure cristalline</term>
<term>Structure magnétique</term>
<term>Propriété magnétique</term>
<term>Lumière verte</term>
<term>Synthèse hydrothermale</term>
<term>Réseau orthorhombique</term>
<term>Groupe espace</term>
<term>Paramètre cristallin</term>
<term>Effet tunnel</term>
<term>Ion sodium</term>
<term>Spectre IR</term>
<term>Susceptibilité magnétique</term>
<term>Antiferromagnétisme</term>
<term>Aimantation</term>
<term>Nickel</term>
<term>Matériau paramagnétique</term>
<term>Matériau antiferromagnétique</term>
<term>Antiferromagnétique</term>
<term>6166</term>
<term>7550E</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Nickel</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Na<sub>2</sub>
Ni(HPO<sub>3</sub>
)<sub>2</sub>
, obtained as light yellow-green crystals under mild hydrothermal conditions, crystallizes in the orthorhombic Pnma space-group with lattice parameters: a = 11.9886(3), b = 5.3671(2), c=9.0764(3) Å. V<sub>=</sub>
584.01 Å<sup>3</sup>
, Z<sub>=</sub>
4. The structure consists of zig-zag chains of Ni0<sub>6</sub>
 octahedra bridged by two HPO<sup>2-</sup>
<sub>3</sub>
 and the chains are further connected through HPO<sup>2-</sup>
<sub>3</sub>
 to four nearest chains to form a three dimensional framework, delimiting intersecting tunnels in which the sodium ions are located. The Na cations reside in the irregular Na(1)O<sub>5</sub>
, Na-O of 2.276-2.745 Å, and Na(2)O<sub>9</sub>
, Na-O of 2.342-2.376 Å, environments. The presence of the phosphite monoanion has been further confirmed by IR spectroscopy. Due to the 3D framework of Ni connected by O-P-O bridges, the magnetic susceptibility behaves as a paramagnet above 100 K (C = 1.49(2) emu K mol<sup>-1</sup>
, μ<sub>eff </sub>
= 3.45 μ<sub>B</sub>
, Θ= -39(2) K) and below 6 K, it orders antiferromagnetically as confirmed the sharp drop and the non-Brillouin behavior of the isothermal magnetization at 2 K.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Tunisie</li>
</country>
<region><li>Alsace (région administrative)</li>
<li>Grand Est</li>
</region>
<settlement><li>Strasbourg</li>
</settlement>
<orgName><li>Université de Strasbourg</li>
</orgName>
</list>
<tree><country name="France"><region name="Grand Est"><name sortKey="Maalej, Wassim" sort="Maalej, Wassim" uniqKey="Maalej W" first="Wassim" last="Maalej">Wassim Maalej</name>
</region>
<name sortKey="Kurmoo, Mohamedally" sort="Kurmoo, Mohamedally" uniqKey="Kurmoo M" first="Mohamedally" last="Kurmoo">Mohamedally Kurmoo</name>
<name sortKey="Vilminot, Serge" sort="Vilminot, Serge" uniqKey="Vilminot S" first="Serge" last="Vilminot">Serge Vilminot</name>
</country>
<country name="Tunisie"><noRegion><name sortKey="Maalej, Wassim" sort="Maalej, Wassim" uniqKey="Maalej W" first="Wassim" last="Maalej">Wassim Maalej</name>
</noRegion>
<name sortKey="Elaoud, Zakaria" sort="Elaoud, Zakaria" uniqKey="Elaoud Z" first="Zakaria" last="Elaoud">Zakaria Elaoud</name>
<name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name>
</country>
</tree>
</affiliations>
</record>

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Crystal structure and magnetic properties of Na2NiII(HPO3)2

Crystal structure and magnetic properties of Na2NiII(HPO3)2

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri